Porous Organic Framework Materials (MOF, COF, and HOF) as the Multifunctional Separator for Rechargeable Lithium Metal Batteries
By
Yang, Y (Yang, Yan) [1] ; Sun, ZY (Sun, Zhaoyu) [1] ; Wu, YW (Wu, Yiwen) [1] ; Liang, ZW (Liang, Ziwei) [1] ; Li, FK (Li, Fangkun) [1] ; Zhu, M (Zhu, Min) [1] ; Liu, J (Liu, Jun) [1]
(provided by Clarivate)
Source
SMALL
Volume20Issue37
DOI10.1002/smll.202401457
Published
SEP 2024
Early Access
MAY 2024
Indexed
2024-05-17
Document Type
Review
Abstract
The separator is an important component in batteries, with the primary function of separating the positive and negative electrodes and allowing the free passage of ions. Porous organic framework materials have a stable connection structure, large specific surface area, and ordered pores, which are natural places to store electrolytes. And these materials with specific functions can be designed according to the needs of researchers. The performance of porous organic framework-based separators used in rechargeable lithium metal batteries is much better than that of polyethylene/propylene separators. In this paper, the three most classic organic framework materials (MOF, COF, and HOF) are analyzed and summarized. The applications of MOF, COF, and HOF separators in lithium-sulfur batteries, lithium metal anode, and solid electrolytes are reviewed. Meanwhile, the research progress of these three materials in different fields is discussed based on time. Finally, in the conclusion, the problems encountered by MOF, COF, and HOF in different fields as well as their future research priorities are presented. This review will provide theoretical guidance for the design of porous framework materials with specific functions and further stimulate researchers to conduct research on porous framework materials.
This review systematically analyzes and summarizes the three most classical materials (MOF, COF, and HOF) among the porous framework materials, and outlines the applications of MOF, COF, and HOF-based separators in lithium metal batteries in terms of blocking the shuttle of polysulfide lithium, inhibiting the formation of lithium dendrite, and improving the electrochemical performance of solid-state electrolytes. image
Keywords
Author Keywordslithium-sulfur batterieslithium dendriteporous framework materialseparatorsolid-state electrolyte
Keywords PlusSURFACE-CHARGE DENSITYSULFUR BATTERYELECTROLYTESCONVERSIONDESIGNANODES
Author Information
Corresponding Address
Liu, Jun
(corresponding author)
South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
Affiliation
South China University of Technology
South China University of Technology Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials
South China University of Technology School of Materials Science and Engineering
E-mail Addresses
msjliu@scut.edu.cn
Addresses
1 South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
E-mail Addresses
msjliu@scut.edu.cn
Categories/ Classification
Research AreasChemistryScience & Technology - Other TopicsMaterials SciencePhysics
Citation Topics
2 Chemistry
2.62 Electrochemistry
2.62.616 Lithium-Sulfur Batteries
Sustainable Development Goals
11 Sustainable Cities and Communities
Web of Science Categories
Chemistry, MultidisciplinaryChemistry, PhysicalNanoscience & NanotechnologyMaterials Science, MultidisciplinaryPhysics, AppliedPhysics, Condensed Matter