Porous Organic Framework Materials (MOF, COF, and HOF) as the Multifunctional Separator for Rechargeable Lithium Metal Batteries

时间:2024-10-11作者:浏览量:97


Porous Organic Framework Materials (MOF, COF, and HOF) as the Multifunctional Separator for Rechargeable Lithium Metal Batteries

By

Yang, Y (Yang, Yan) [1] ; Sun, ZY (Sun, Zhaoyu) [1] ; Wu, YW (Wu, Yiwen) [1] ; Liang, ZW (Liang, Ziwei) [1] ; Li, FK (Li, Fangkun) [1] ; Zhu, M (Zhu, Min) [1] ; Liu, J (Liu, Jun) [1]

 (provided by Clarivate) 

Source

SMALL

Volume20Issue37

DOI10.1002/smll.202401457

Published

SEP 2024

Early Access

MAY 2024

Indexed

2024-05-17

Document Type

Review

Abstract

The separator is an important component in batteries, with the primary function of separating the positive and negative electrodes and allowing the free passage of ions. Porous organic framework materials have a stable connection structure, large specific surface area, and ordered pores, which are natural places to store electrolytes. And these materials with specific functions can be designed according to the needs of researchers. The performance of porous organic framework-based separators used in rechargeable lithium metal batteries is much better than that of polyethylene/propylene separators. In this paper, the three most classic organic framework materials (MOF, COF, and HOF) are analyzed and summarized. The applications of MOF, COF, and HOF separators in lithium-sulfur batteries, lithium metal anode, and solid electrolytes are reviewed. Meanwhile, the research progress of these three materials in different fields is discussed based on time. Finally, in the conclusion, the problems encountered by MOF, COF, and HOF in different fields as well as their future research priorities are presented. This review will provide theoretical guidance for the design of porous framework materials with specific functions and further stimulate researchers to conduct research on porous framework materials.

This review systematically analyzes and summarizes the three most classical materials (MOF, COF, and HOF) among the porous framework materials, and outlines the applications of MOF, COF, and HOF-based separators in lithium metal batteries in terms of blocking the shuttle of polysulfide lithium, inhibiting the formation of lithium dendrite, and improving the electrochemical performance of solid-state electrolytes. image

Keywords

Author Keywordslithium-sulfur batterieslithium dendriteporous framework materialseparatorsolid-state electrolyte

Keywords PlusSURFACE-CHARGE DENSITYSULFUR BATTERYELECTROLYTESCONVERSIONDESIGNANODES

Author Information

Corresponding Address

Liu, Jun

(corresponding author)

South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China

Affiliation

South China University of Technology

South China University of Technology Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials

South China University of Technology School of Materials Science and Engineering

E-mail Addresses 

msjliu@scut.edu.cn

Addresses 

1 South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China

E-mail Addresses 

msjliu@scut.edu.cn

Categories/ Classification

Research AreasChemistryScience & Technology - Other TopicsMaterials SciencePhysics

Citation Topics

2 Chemistry

2.62 Electrochemistry

2.62.616 Lithium-Sulfur Batteries

Sustainable Development Goals

11 Sustainable Cities and Communities

Web of Science Categories

Chemistry, MultidisciplinaryChemistry, PhysicalNanoscience & NanotechnologyMaterials Science, MultidisciplinaryPhysics, AppliedPhysics, Condensed Matter