Facile synthesis of black phosphorene via a low melting media assisted ball milling

时间:2022-07-05作者:浏览量:23


Facile synthesis of black phosphorene via a low melting media assisted ball milling

作者:

Zhou, FC (Zhou, Fengchen) [1] ; Li, SB (Li, Shaobo) [1] ; Ouyang, LZ (Ouyang, Liuzhang) [1] , [2] ; Liu, JW (Liu, Jiangwen) [1] ; Liu, J (Liu, Jun) [1] ; Huang, ZG (Huang, Zhenguo) [3] ; Zhu, M (Zhu, Min) [1]

查看 Web of Science ResearcherID 和 ORCID (由 Clarivate 提供) CHEMICAL ENGINEERING JOURNAL

卷444

文献号136593

DOI10.1016/j.cej.2022.136593

出版时间SEP 15 2022

已索引2022-06-08

文献类型Article

摘要

Few-layer phosphorene (FLP) has attracted strong research interest due to its extraordinary physical and chemical properties. However, an efficient and rapid fabrication of high-quality FLP is still unavailable. Herein, a simple and efficient low melting media-assisted ball milling (LMMBM) approach is developed to prepare FLP in large quantities. The phase change of the LMM at higher temperatures leads to FLP with larger lateral dimensions compared to the ones obtained via dry solid state ball milling. Transmission electron microscope (TEM) studies indicated that liquid facilitates the slipping/curling of black phosphorus (BP) layers under the shearing force generated during ball milling. When used as an anode in Lithium-ion batteries, the FLP-C composite exhibits high initial Coulombic efficiency, stable cycling and rate capacity. This LMMBM approach can be adopted for mass production of other two-dimensional materials from their bulk counterparts.


关键词

作者关键词Few-layer black phosphorusPhosphoreneBall millingLow melting mediaLithium-ion battery

Keywords PlusEXFOLIATIONPERFORMANCEGROWTHANODE

作者信息

通讯作者地址

Ouyang, Liuzhang

(通讯作者)

South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China

通讯作者地址

Huang, Zhenguo

(通讯作者)

Univ Technol Sydney, Sch Civil & Environm Engn, Sydney, NSW 2007, Australia

地址

1 South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China

2 China Australia Joint Lab Energy & Environm Mat, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510641, Peoples R China

3 Univ Technol Sydney, Sch Civil & Environm Engn, Sydney, NSW 2007, Australia

电子邮件地址meouyang@scut.edu.cnzhenguo.huang@uts.edu.au

类别/分类

研究方向Engineering