Facile synthesis of black phosphorene via a low melting media assisted ball milling
作者:
Zhou, FC (Zhou, Fengchen) [1] ; Li, SB (Li, Shaobo) [1] ; Ouyang, LZ (Ouyang, Liuzhang) [1] , [2] ; Liu, JW (Liu, Jiangwen) [1] ; Liu, J (Liu, Jun) [1] ; Huang, ZG (Huang, Zhenguo) [3] ; Zhu, M (Zhu, Min) [1]
查看 Web of Science ResearcherID 和 ORCID (由 Clarivate 提供) CHEMICAL ENGINEERING JOURNAL
卷444
文献号136593
DOI10.1016/j.cej.2022.136593
出版时间SEP 15 2022
已索引2022-06-08
文献类型Article
摘要
Few-layer phosphorene (FLP) has attracted strong research interest due to its extraordinary physical and chemical properties. However, an efficient and rapid fabrication of high-quality FLP is still unavailable. Herein, a simple and efficient low melting media-assisted ball milling (LMMBM) approach is developed to prepare FLP in large quantities. The phase change of the LMM at higher temperatures leads to FLP with larger lateral dimensions compared to the ones obtained via dry solid state ball milling. Transmission electron microscope (TEM) studies indicated that liquid facilitates the slipping/curling of black phosphorus (BP) layers under the shearing force generated during ball milling. When used as an anode in Lithium-ion batteries, the FLP-C composite exhibits high initial Coulombic efficiency, stable cycling and rate capacity. This LMMBM approach can be adopted for mass production of other two-dimensional materials from their bulk counterparts.
关键词
作者关键词Few-layer black phosphorusPhosphoreneBall millingLow melting mediaLithium-ion battery
Keywords PlusEXFOLIATIONPERFORMANCEGROWTHANODE
作者信息
通讯作者地址
Ouyang, Liuzhang
(通讯作者)
South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
通讯作者地址
Huang, Zhenguo
(通讯作者)
Univ Technol Sydney, Sch Civil & Environm Engn, Sydney, NSW 2007, Australia
地址
1 South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
2 China Australia Joint Lab Energy & Environm Mat, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510641, Peoples R China
3 Univ Technol Sydney, Sch Civil & Environm Engn, Sydney, NSW 2007, Australia
电子邮件地址meouyang@scut.edu.cnzhenguo.huang@uts.edu.au
类别/分类
研究方向Engineering