Hydrogen Production via Hydrolysis and Alcoholysis of Light Metal-Based Materials: A Review
作者
Ouyang, LZ (Ouyang, Liuzhang) 1, 2
Jiang, J (Jiang, Jun) 1
Chen, K (Chen, Kang) 1
Zhu, M (Zhu, Min) 1, 2
Liu, ZW (Liu, Zongwen) 3, 4
查看 Web of Science ResearcherID 和 ORCID (由 Clarivate 提供) NANO-MICRO LETTERS
卷13
期1
文献号134
DOI10.1007/s40820-021-00657-9
出版时间DEC 2021
文献类型Review
摘要
As an environmentally friendly and high-density energy carrier, hydrogen has been recognized as one of the ideal alternatives for fossil fuels. One of the major challenges faced by hydrogen economy is the development of efficient, low-cost, safe and selective hydrogen generation from chemical storage materials. In this review, we summarize the recent advances in hydrogen production via hydrolysis and alcoholysis of light-metal-based materials, such as borohydrides, Mg-based and Al-based materials, and the highly efficient regeneration of borohydrides. Unfortunately, most of these hydrolysable materials are still plagued by sluggish kinetics and low hydrogen yield. While a number of strategies including catalysis, alloying, solution modification, and ball milling have been developed to overcome these drawbacks, the high costs required for the one-pass utilization of hydrolysis/alcoholysis systems have ultimately made these techniques almost impossible for practical large-scale applications. Therefore, it is imperative to develop low-cost material systems based on abundant resources and effective recycling technologies of spent fuels for efficient transport, production and storage of hydrogen in a fuel cell-based hydrogen economy.
关键词
作者关键词HydrolysisAlcoholysisLight metal-based materialsBorohydridesMagnesiumAluminumHydrogen production
Keywords PlusSODIUM-BOROHYDRIDE HYDROLYSISENHANCED KINETICS PERFORMANCECOBALT-PHOSPHORUS CATALYSTSMICRO-FUEL-CELLACTIVATED AL-BIGENERATION PERFORMANCEEFFICIENT CATALYSTSTORAGE MATERIALSAMMONIA-BORANESUPPORTED CO
作者信息
通讯作者地址
Ouyang, Liuzhang
(通讯作者)
South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
通讯作者地址
Ouyang, Liuzhang
(通讯作者)
Key Lab Fuel Cell Technol Guangdong Prov, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Peoples R China
通讯作者地址
Liu, Zongwen
(通讯作者)
Univ Sydney, Sch Chem & Biomol Engn, Sydney, NSW 2006, Australia
通讯作者地址
Liu, Zongwen
(通讯作者)
Univ Sydney, Nano Inst, Sydney, NSW 2006, Australia
地址
1 South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
2 Key Lab Fuel Cell Technol Guangdong Prov, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Peoples R China
3 Univ Sydney, Sch Chem & Biomol Engn, Sydney, NSW 2006, Australia
4 Univ Sydney, Nano Inst, Sydney, NSW 2006, Australia
电子邮件地址meouyang@scut.edu.cnzongwen.liu@sydney.edu.au
类别/分类
研究方向Science & Technology - Other TopicsMaterials SciencePhysics