Multifunctional Metal Phosphides as Superior Host Materials for Advanced Lithium-Sulfur Batteries
作者
Wang, ZS (Wang, Zhuosen) 1
Xu, XJ (Xu, Xijun) 2
Liu, ZB (Liu, Zhengbo) 2
Zhang, DC (Zhang, Dechao) 2
Yuan, JJ (Yuan, Jujun) 3
Liu, J (Liu, Jun) 2, 3
查看 Web of Science ResearcherID 和 ORCID (由 Clarivate 提供) CHEMISTRY-A EUROPEAN JOURNAL
卷27
期54
页13494-13512
DOI10.1002/chem.202101873
出版时间SEP 24 2021
在线发表AUG 2021
文献类型Review
摘要
For the past few years, a new generation of energy storage systems with large theoretical specific capacity has been urgently needed because of the rapid development of society. Lithium-sulfur (Li-S) batteries are regarded as one of the most promising candidates for novel battery systems, since their resurgence at the end of the 20th century Li-S batteries have attracted ever more attention, attributed to their notably high theoretical energy density of 2600 W h kg(-1), which is almost five times larger than that of commercial lithium-ion batteries (LIBs). One of the determining factors in Li-S batteries is how to design/prepare the sulfur cathode. For the sulfur host, the major technical challenge is avoiding the shuttling effect that is caused by soluble polysulfides during the reaction. In past decades, though the sulfur cathode has developed greatly, there are still some enormous challenges to be conquered, such as low utilization of S, rapid decay of capacity, and poor cycle life. This article spotlights the recent progress and foremost findings in improving the performance of Li-S batteries by employing multifunctional metal phosphides as host materials. The current state of development of the sulfur electrode of Li-S batteries is summarized by emphasizing the relationship between the essential properties of metal phosphide-based hybrid nanomaterials, the chemical reaction with lithium polysulfides and the latter ' s influence on electrochemical performance. Finally, trends in the development and practical application of Li-S batteries are also pointed out.
关键词
作者关键词Li-ion batterieshigh-energy densitysulfurmetal phosphides
Keywords PlusONE-POT SYNTHESISCOBALT PHOSPHIDEPOLYSULFIDE RESERVOIRCARBON NANOTUBESFACILE SYNTHESISANODE MATERIALHIGH-CAPACITYLOW-COSTNI-PPERFORMANCE
作者信息
通讯作者地址
Liu, Jun
(通讯作者)
South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
通讯作者地址
Yuan, Jujun;Liu, Jun
(通讯作者)
Gannan Normal Univ, Sch Phys & Elect, Ganzhou 341000, Peoples R China
地址
1 Zhengzhou Univ, Henan Inst Adv Technol, Zhengzhou 450052, Peoples R China
2 South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
3 Gannan Normal Univ, Sch Phys & Elect, Ganzhou 341000, Peoples R China
电子邮件地址yuanjujun123@163.commsjliu@scut.edu.cn
类别/分类
研究方向Chemistry