Hydrogen Production via Hydrolysis and Alcoholysis of Light Metal-Based Materials: A Review

时间:2021-09-16作者:浏览量:389


Hydrogen Production via Hydrolysis and Alcoholysis of Light Metal-Based Materials: A Review

作者:Ouyang, LZ (Ouyang, Liuzhang)[ 1,2 ] ; Jiang, J (Jiang, Jun)[ 1 ] ; Chen, K (Chen, Kang)[ 1 ] ; Zhu, M (Zhu, Min)[ 1,2 ] ; Liu, ZW (Liu, Zongwen)[ 3,4 ]

 

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NANO-MICRO LETTERS

 

: 13 : 1

文献号: 134

 

DOI: 10.1007/s40820-021-00657-9

 

出版年: DEC 2021

 

文献类型:Review

 

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摘要

As an environmentally friendly and high-density energy carrier, hydrogen has been recognized as one of the ideal alternatives for fossil fuels. One of the major challenges faced by hydrogen economy is the development of efficient, low-cost, safe and selective hydrogen generation from chemical storage materials. In this review, we summarize the recent advances in hydrogen production via hydrolysis and alcoholysis of light-metal-based materials, such as borohydrides, Mg-based and Al-based materials, and the highly efficient regeneration of borohydrides. Unfortunately, most of these hydrolysable materials are still plagued by sluggish kinetics and low hydrogen yield. While a number of strategies including catalysis, alloying, solution modification, and ball milling have been developed to overcome these drawbacks, the high costs required for the one-pass utilization of hydrolysis/alcoholysis systems have ultimately made these techniques almost impossible for practical large-scale applications. Therefore, it is imperative to develop low-cost material systems based on abundant resources and effective recycling technologies of spent fuels for efficient transport, production and storage of hydrogen in a fuel cell-based hydrogen economy.

 

关键词

作者关键词:Hydrolysis; Alcoholysis; Light metal-based materials; Borohydrides; Magnesium; Aluminum; Hydrogen production

 

KeyWords Plus:SODIUM-BOROHYDRIDE HYDROLYSIS; ENHANCED KINETICS PERFORMANCE; COBALT-PHOSPHORUS CATALYSTS; MICRO-FUEL-CELL; ACTIVATED AL-BI; GENERATION PERFORMANCE; EFFICIENT CATALYST; STORAGE MATERIALS; AMMONIA-BORANE; SUPPORTED CO

 

作者信息

通讯作者地址:

 

South China University of Technology South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China.

Key Lab Fuel Cell Technol Guangdong Prov, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Peoples R China.

University of Sydney Univ Sydney, Sch Chem & Biomol Engn, Sydney, NSW 2006, Australia.

University of Sydney Univ Sydney, Nano Inst, Sydney, NSW 2006, Australia.

通讯作者地址: Ouyang, LZ (通讯作者)

 

显示更多       South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China.

通讯作者地址: Ouyang, LZ (通讯作者)

          Key Lab Fuel Cell Technol Guangdong Prov, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Peoples R China.

通讯作者地址: Liu, ZW (通讯作者)

显示更多       Univ Sydney, Sch Chem & Biomol Engn, Sydney, NSW 2006, Australia.

通讯作者地址: Liu, ZW (通讯作者)

显示更多       Univ Sydney, Nano Inst, Sydney, NSW 2006, Australia.

地址:

 

显示更多       [ 1 ] South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China

          [ 2 ] Key Lab Fuel Cell Technol Guangdong Prov, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Peoples R China

显示更多       [ 3 ] Univ Sydney, Sch Chem & Biomol Engn, Sydney, NSW 2006, Australia

显示更多       [ 4 ] Univ Sydney, Nano Inst, Sydney, NSW 2006, Australia

电子邮件地址:meouyang@scut.edu.cn; zongwen.liu@sydney.edu.au

 

基金资助致谢

基金资助机构显示详情       授权号

National Key R&D Program of China

 

2018YFB1502101

National Natural Science Foundation of China (NSFC)

 

NSFC51621001

National Natural Science Foundation of China (NSFC)

 

51771075

National Natural Science Foundation of Guangdong Province

 

2016A030312011

Australian Research Council

 

DP180102976

DP210103539

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出版商

SHANGHAI JIAO TONG UNIV PRESS, SHANGHAI JIAO TONG UNIV, 800 DONGCHUAN RD, SHANGHAI, 200240, PEOPLES R CHINA

 

期刊信息

Impact Factor (影响因子): Journal Citation Reports

类别 / 分类

研究方向:Science & Technology - Other Topics; Materials Science; Physics

 

Web of Science 类别:Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied