Multifunctional Metal Phosphides as Superior Host Materials for Advanced Lithium-Sulfur Batteries
作者:Wang, ZS (Wang, Zhuosen)[ 1 ] ; Xu, XJ (Xu, Xijun)[ 2 ] ; Liu, ZB (Liu, Zhengbo)[ 2 ] ; Zhang, DC (Zhang, Dechao)[ 2 ] ; Yuan, JJ (Yuan, Jujun)[ 3 ] ; Liu, J (Liu, Jun)[ 2,3 ]
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CHEMISTRY-A EUROPEAN JOURNAL
DOI: 10.1002/chem.202101873
Early access icon在线发表日期: AUG 2021
文献类型:Review; Early Access
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摘要
For the past few years, a new generation of energy storage systems with large theoretical specific capacity has been urgently needed because of the rapid development of society. Lithium-sulfur (Li-S) batteries are regarded as one of the most promising candidates for novel battery systems, since their resurgence at the end of the 20th century Li-S batteries have attracted ever more attention, attributed to their notably high theoretical energy density of 2600 W h kg(-1), which is almost five times larger than that of commercial lithium-ion batteries (LIBs). One of the determining factors in Li-S batteries is how to design/prepare the sulfur cathode. For the sulfur host, the major technical challenge is avoiding the shuttling effect that is caused by soluble polysulfides during the reaction. In past decades, though the sulfur cathode has developed greatly, there are still some enormous challenges to be conquered, such as low utilization of S, rapid decay of capacity, and poor cycle life. This article spotlights the recent progress and foremost findings in improving the performance of Li-S batteries by employing multifunctional metal phosphides as host materials. The current state of development of the sulfur electrode of Li-S batteries is summarized by emphasizing the relationship between the essential properties of metal phosphide-based hybrid nanomaterials, the chemical reaction with lithium polysulfides and the latter ' s influence on electrochemical performance. Finally, trends in the development and practical application of Li-S batteries are also pointed out.
关键词
作者关键词:Li-ion batteries; high-energy density; sulfur; metal phosphides
KeyWords Plus:ONE-POT SYNTHESIS; COBALT PHOSPHIDE; POLYSULFIDE RESERVOIR; CARBON NANOTUBES; FACILE SYNTHESIS; ANODE MATERIAL; HIGH-CAPACITY; LOW-COST; NI-P; PERFORMANCE
作者信息
通讯作者地址:
South China University of Technology South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China.
Gannan Normal University Gannan Normal Univ, Sch Phys & Elect, Ganzhou 341000, Peoples R China.
通讯作者地址: Liu, J (通讯作者)
显示更多 South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China.
通讯作者地址: Yuan, JJ; Liu, J (通讯作者)
显示更多 Gannan Normal Univ, Sch Phys & Elect, Ganzhou 341000, Peoples R China.
地址:
显示更多 [ 1 ] Zhengzhou Univ, Henan Inst Adv Technol, Zhengzhou 450052, Peoples R China
显示更多 [ 2 ] South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
显示更多 [ 3 ] Gannan Normal Univ, Sch Phys & Elect, Ganzhou 341000, Peoples R China
电子邮件地址:yuanjujun123@163.com; msjliu@scut.edu.cn
基金资助致谢
基金资助机构显示详情 授权号
National Natural Science Foundation of China (NSFC)
51771076
NSFC51621001
Guangdong Pearl River Talents Plan
2017GC010218
R&D Program in Key Areas of Guangdong Province
2020B0101030005
Guangdong Basic and Applied Basic Research Foundation
2020B1515120049
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出版商
WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
期刊信息
Impact Factor (影响因子): Journal Citation Reports
类别 / 分类
研究方向:Chemistry
Web of Science 类别:Chemistry, Multidisciplinary