Closing the Loop for Hydrogen Storage: Facile Regeneration of NaBH4 from its Hydrolytic Product
作者:Zhu, YY (Zhu, Yongyang)[ 1 ] ; Ouyang, LZ (Ouyang, Liuzhang)[ 1,2 ] ; Zhong, H (Zhong, Hao)[ 1 ] ; Liu, JW (Liu, Jiangwen)[ 1 ] ; Wang, H (Wang, Hui)[ 1 ] ; Shao, HY (Shao, Huaiyu)[ 3 ] ; Huang, ZG (Huang, Zhenguo)[ 4 ] ; Zhu, M (Zhu, Min)[ 1 ]
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷: 59 期: 22 页: 8623-8629
DOI: 10.1002/anie.201915988
出版年: MAY 25 2020
文献类型:Article
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摘要
Sodium borohydride (NaBH4) is among the most studied hydrogen storage materials because it is able to deliver high-purity H-2 at room temperature with controllable kinetics via hydrolysis; however, its regeneration from the hydrolytic product has been challenging. Now, a facile method is reported to regenerate NaBH4 with high yield and low costs. The hydrolytic product NaBO2 in aqueous solution reacts with CO2, forming Na2B4O7.10 H2O and Na2CO3, both of which are ball-milled with Mg under ambient conditions to form NaBH4 in high yield (close to 80 %). Compared with previous studies, this approach avoids expensive reducing agents such as MgH2, bypasses the energy-intensive dehydration procedure to remove water from Na2B4O7.10 H2O, and does not require high-pressure H-2 gas, therefore leading to much reduced costs. This method is expected to effectively close the loop of NaBH4 regeneration and hydrolysis, enabling a wide deployment of NaBH4 for hydrogen storage.
关键词
作者关键词:borohydride; hydrogen; hydrogen storage; hydrolysis; regeneration
KeyWords Plus:SODIUM-BOROHYDRIDE; MECHANOCHEMICAL REACTION; THERMAL-DECOMPOSITION; GENERATION; METABORATE; DEHYDRATION; MAGNESIUM; HYDRIDES; USAGE; NABO2
作者信息
通讯作者地址: Ouyang, LZ (通讯作者)
显示更多South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China.
通讯作者地址: Ouyang, LZ (通讯作者)
Key Lab Fuel Cell Technol Guangdong Prov, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Peoples R China.
通讯作者地址: Shao, HY (通讯作者)
显示更多Univ Macau, Inst Appl Phys & Mat Engn, Fac Sci & Technol, Joint Key Lab,Minist Educ,Dept Phys & Chem, Taipa, Macau, Peoples R China.
通讯作者地址: Huang, ZG (通讯作者)
显示更多Univ Technol Sydney, Sch Civil & Environm Engn, Sydney, NSW 2007, Australia.
地址:
显示更多[ 1 ] South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China
[ 2 ] Key Lab Fuel Cell Technol Guangdong Prov, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Peoples R China
显示更多[ 3 ] Univ Macau, Inst Appl Phys & Mat Engn, Fac Sci & Technol, Joint Key Lab,Minist Educ,Dept Phys & Chem, Taipa, Macau, Peoples R China
显示更多[ 4 ] Univ Technol Sydney, Sch Civil & Environm Engn, Sydney, NSW 2007, Australia
电子邮件地址:meouyang@scut.edu.cn; hshao@um.edu.mo; zhenguo.huang@uts.edu.au
基金资助致谢
基金资助机构显示详情授权号
Australian Research Council
DP170101773
National Natural Science Foundation of China
No. NSFC51621001
National Natural Science Foundation of China
Nos. 51771075
National Natural Science Foundation of Guangdong Province
2016A030312011
Macau Science and Technology Development Fund (FDCT)
No.: 0062/2018/A2 and 118/2016/A3
Adaptable and Seamless Technology Transfer Program through Target-Driven R and D
No. 2018YFB15-02100
Guangdong Province Higher Vocational Colleges and Schools Pearl River Scholar Funded Scheme
2014
出版商
WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
期刊信息
Impact Factor (影响因子): Journal Citation Reports
类别 / 分类
研究方向:Chemistry
Web of Science 类别:Chemistry, Multidisciplinary