Engineering layer structure of MoS2/polyaniline/graphene nanocomposites to achieve fast and reversible lithium storage for high energy density aqueous lithium-ion capacitors
作者:Chao, J (Chao, Jie)[ 1,2 ] ; Yang, LC (Yang, Lichun)[ 2,3 ] ; Zhang, HY (Zhang, Hanyin)[ 2,3 ] ; Liu, JW (Liu, Jiangwen)[ 2,3 ] ; Hu, RZ (Hu, Renzong)[ 2 ] ; Zhu, M (Zhu, Min)[ 2 ]
JOURNAL OF POWER SOURCES
卷: 450
文献号: 227680
DOI: 10.1016/j.jpowsour.2019.227680
出版年: FEB 29 2020
文献类型:Article
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摘要
In recent years, many efforts are devoted to enhance the energy density of supercapacitors without sacrificing its intrinsic high power density. To achieve this, high energy density aqueous lithium-ion capacitors (LIC) are demonstrated by employing phosphorus-MoS2/polyaniline/reduced graphene oxide hierarchical nanosheets (P-MoS2/PANI/rGO HNSs) anode electrode via a simple organic/inorganic hybridization method. With the phosphorus and PANI intercalate into the adjacent MoS2 layers and then grow on the rGO nanosheets, the P-MoS2/PANI/rGO HNSs has enlarged and disordered interlayer structure and thus obtain improved Li-ion storage capability. Accordingly, an P-MoS2/PANI/rGO HNSs based LIC delivers an energy density of 56.0 Wh kg(-1), when the power density is 0.45 kW kg(-1). Moreover, the capacitance retention of the P-MoS2/PANI/rGO based LIC can be up to 93.5% after 30,000 charge/discharge cycles at a current density of 5 A g(-1), showing great application potential for future electric vehicle.
关键词
作者关键词:Aqueous lithium-ion capacitors; MoS2; P-MoS2/PANI/rGO nanocomposite; P-MoS2/PANI nanosheets; Graphene
KeyWords Plus:MOLYBDENUM-DISULFIDE NANOSHEETS; REDUCED GRAPHENE OXIDE; ELECTROCHEMICAL CAPACITORS; PERFORMANCE; NANOFLOWERS; NANOFIBERS; ANODES; ROBUST
作者信息
通讯作者地址: Zhu, M (通讯作者)
显示更多South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China.
地址:
显示更多[ 1 ] Dongguan Univ Technol, Sch Chem Engn & Energy Technol, Dongguan 523808, Peoples R China
显示更多[ 2 ] South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China
显示更多[ 3 ] South China Univ Technol, SUNWODA SCUT Joint Lab Adv Energy Storage Technol, Guangzhou 510640, Peoples R China
电子邮件地址:chaojie1031@163.com; mslcyang@scut.edu.cn; zhanghanyin@scut.edu.cn; mejwliu@scut.edu.cn; cmsrenzonghu@scut.edu.cn; memzhu@scut.edu.cn
基金资助致谢
基金资助机构显示详情授权号
National Natural Science Foundation of China
NSFC51621001
National Natural Science Foundation of China
51402110
51671089
Guangdong Natural Science Funds for Distinguished Young Scholar
2017B030306004
National Natural Science Foundation of Guangdong Province
2016A030312011
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出版商
ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS
期刊信息
Impact Factor (影响因子): Journal Citation Reports
类别 / 分类
研究方向:Chemistry; Electrochemistry; Energy & Fuels; Materials Science
Web of Science 类别:Chemistry, Physical; Electrochemistry; Energy & Fuels; Materials Science, Multidisciplinary