作者:Liu, YX (Liu, Yuxuan)[1 ]; Lu, ZC (Lu, Zhongchen)[2 ]; Cui, J (Cui, Jie)[3 ]; Liu, H (Liu, Hui)[4 ]; Liu, J (Liu, Jun)[1 ]; Hu, RZ (Hu, Renzong)[1 ]; Zhu, M (Zhu, Min)[1 ]
Poor reversibility of conversion and alloying reactions for Sb2S3 limits its application as high capacity anode for rechargeable lithium storage. Herein a facile high-efficiency plasma assisted milling (P-milling) was used to create Sb2S3-C hybrid nanostructure with disk-like Sb2S3 nanograins wrapped within ultrathin graphite nanosheets. Benefiting from the high structure stability and excellent Li+ ion diffusion kinetics in the graphite wrapped Sb2S3 nanostructure, highly reversible conversion and alloying reactions are maintained throughout the long-term cycles. The Sb2S3-C nanocomposite anode demonstrates a high stable capacity of 638.2 mA h g(-1) after 250 cycles at 200 mA g(-1) between 0.01 and 3.0 V vs. Li/Li+, with a high initial Coulombic efficiency of 78.3%. A reversible capacity of 496.1 mA h g(-1) is obtained after 500 cycles even at higher current rate of 1 A g(-1), much superior to those of the unmilled Sb2S3-C and P-milled Sb2S3 anodes. These demonstrate that P-milling could be a promising strategy to create high performance metal chalcogenide anode materials involved both conversion and alloying reactions toward lithium storage. (C) 2019 Elsevier Ltd. All rights reserved.
作者关键词:Antimony sulfide; Plasma milling; Conversion reactions; Reversibility
KeyWords Plus:CYCLIC DURABLE ANODES; HIGH-CAPACITY ANODE; ELECTROCHEMICAL PERFORMANCE; GRAPHENE NANOSHEETS; ELECTRODE MATERIALS; SB2S3 NANORODS; ION BATTERIES; LONG-LIFE; COMPOSITE; SILICON
通讯作者地址:Hu, RZ (通讯作者)
![]() | South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China. |
![]() | South China Univ Technol, Sch Mech & Automot Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China. |
地址:
基金资助机构 | 授权号 |
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National Natural Science Foundation of China | 51671088 51621001 51822104 51831009 |
Guangzhou Science and Technology Plan Projects | 201707010191 |