Tuning the structural stability of LiBH4 through boron-based compounds towards superior dehydrogenation

标题

Tuning the structural stability of LiBH4 through boron-based compounds towards superior dehydrogenation

作者

作者:Cai, WT (Cai, Weitong)^[1 ]; Chen, JE (Chen, Juner)^[2 ]; Liu, LY (Liu, Liying)^[1 ]; Yang, YZ (Yang, Yuanzheng)^[1 ]; Wang, H (Wang, Hui)^[3,4 ]

期刊信息

摘要

The remarkable destabilization effects of H3BO3, HBO2, and B2O3 on dehydrogenation of LiBH4 are revealed in this work. The effectiveness of destabilizing the structural stability is in the order of H3BO3 > HBO2 > B2O3. Besides, through optimizing the molar ratio of LiBH4 and H3BO3 and milling treatment, the destabilization effect, especially for dehydrogenation kinetics, is further enhanced. For example, at a temperature as low as 110 degrees C, 5.8 wt% hydrogen can be liberated in seconds from 2LiBH(4)-H3BO3 prepared through pre-milling. The investigation reveals that each of the LiBH4-H3BO3, LiBH4-HBO2 and LiBH4-B2O3 systems undergo multiple dehydrogenation stages corresponding to different destabilization mechanisms. The reaction at lower temperature is ascribed to the H+ center dot center dot center dot H- coupling mechanism which should be enhanced by the [OH] center dot center dot center dot [BH4](-) interaction mode. Pre-milling treatment of LiBH4 and H3BO3 also promotes the H+ center dot center dot center dot H- interaction which may have originated from the increasing contact area as a result of the fine particles, and therefore probably reduced the reaction activation energy. Consequently, it gives rise to the superior dehydrogenation performance of lower temperature, rapid kinetics, pure hydrogen and high capacity, which are required for off-board hydrogen energy vehicle application.

关键词

KeyWords Plus:REVERSIBLE HYDROGEN STORAGE; N-H SYSTEM; METAL-BOROHYDRIDES; THERMODYNAMICAL STABILITIES; DECOMPOSITION PATHWAY; COMPOSITE; PRESSURE; DESORPTION; CARBON; NANOCONFINEMENT

作者信息

作者信息

通讯作者地址:Cai, WT (通讯作者)

Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Guangdong, Peoples R China.   增强组织信息的名称     Guangdong University of Technology

通讯作者地址:Wang, H (通讯作者)

South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China.   增强组织信息的名称     South China University of Technology

通讯作者地址:Wang, H (通讯作者)

Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China.

地址:

	[ 1 ] Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Guangdong, Peoples R China   增强组织信息的名称     Guangdong University of Technology
	[ 2 ] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China   增强组织信息的名称     Zhejiang University
	[ 3 ] South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China   增强组织信息的名称     South China University of Technology
	[ 4 ] Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China

电子邮件地址:mewtcai@gdut.edu.cn; mehwang@scut.edu.cn

出版商

ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND

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