MoS2 Nanosheets with Conformal Carbon Coating as Stable Anode Materials for Sodium-Ion Batteries

时间:2018-05-25作者:浏览量:370


标题

MoS2 Nanosheets with Conformal Carbon Coating as Stable Anode Materials for Sodium-Ion Batteries

作者

作者:Li, X (Li, Xiang)[1 ]; Li, JH (Li, Junhao)[2 ]; Gao, QS (Gao, Qingsheng)[2 ]; Yu, X (Yu, Xiang)[2 ]; Hu, RZ (Hu, Renzong)[1 ]; Liu, J (Liu, Jun)[1 ]; Yang, LC (Yang, Lichun)[1 ]; Zhu, M (Zhu, Min)[1 ]

期刊信息


ELECTROCHIMICA ACTA


卷:254

页:172-180

DOI:10.1016/j.electacta.2017.09.128

出版年:NOV 10 2017

文献类型:Article

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摘要

MoS2 nanosheets with conformal carbon coating are achieved via a facile, chemical vapor deposition process, employing ethanol vapor as carbon source. The uniform carbon layers are semi-graphitized, which facilitate kinetics for electron and ion transfer, accommodate volume variation of MoS2, and relieve dissolution of polysulfide during repeated discharge/charge cycles. As anode materials for sodium-ion batteries, the optimized carbon coated MoS2 nanosheets show stable reversible capacity of 500 mAh g(-1) for 100 cycles at 0.1 Ag-1, and maintain 351.6 mAh g(-1) after 200 cycles even at 1 Ag-1. Furthermore, the enhanced electron transfer, and the stabilized structure are verified through electrochemical impedance spectroscopy, cyclic voltammetry, as well as scanning electron microscopy. Our results show that the carbon coating by chemical vapor deposition is efficient and promising to improve the reversible Na+ storage performance of anode materials. (C) 2017 Elsevier Ltd. All rights reserved.

关键词

作者关键词:carbon coating; cycle stability; anode; MoS2; sodium-ion battery

作者信息

作者信息

通讯作者地址:Yang, LC (通讯作者)

显示更多South China Univ Technol, Guangdong Prov Key Lab Adv Energy Storage Mat, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China.


地址:

显示更多[ 1 ] South China Univ Technol, Guangdong Prov Key Lab Adv Energy Storage Mat, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China
显示更多[ 2 ] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China


电子邮件地址:mslcyang@scut.edu.cn

出版商

PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

类别分类

类别 / 分类

研究方向:Electrochemistry

Web of Science 类别:Electrochemistry