Surface Modification of Na3V2(PO4)(3) by Nitrogen and Sulfur Dual-Doped Carbon Layer with Advanced Sodium Storage Property

时间:2018-05-25作者:浏览量:616


标题

Surface Modification of Na3V2(PO4)(3) by Nitrogen and Sulfur Dual-Doped Carbon Layer with Advanced Sodium Storage Property

作者

作者:Liang, XH (Liang, Xinghui)[1 ]; Ou, X (Ou, Xing)[1 ]; Zheng, FH (Zheng, Fenghua)[1 ]; Pan, QC (Pan, Qichang)[1 ]; Xiong, XH (Xiong, Xunhui)[1 ]; Hu, RZ (Hu, Renzong)[2 ]; Yang, CH (Yang, Chenghao)[1 ]; Liu, ML (Liu, Meilin)[1,3 ]

期刊信息


ACS APPLIED MATERIALS & INTERFACES


卷:9

期:15

页:13151-13162

DOI:10.1021/acsami.7b00818

出版年:APR 19 2017

文献类型:Article

查看期刊影响力

摘要

Nitrogen and sulfur dual-doped carbon layer wrapped Na3V2(PO4)(3) nanoparticles (NVP@NSC) have been successfully fabricated by the facile solid-state method. In this hierarchical structure, the Na3V2(PO4)(3) nanoparticlesare well dispersed and closely coated by nitrogen and sulfur dual-doped carbon layer, constructing an effective and interconnected conducting network to reduce the internal resistance. :Furthermore, the uniform coating layers alleviate the agglomeration of Na3V2(PO4)(3) as well as mitigate the side reaction between electrode and electrolyte. Because of the excellent electron transfer mutually enhancing sodium diffuion for this extraordinary structure, the NVP@NSC composite delivers an impressive discharge capacity of 113.0 mAh g(-1) at 1 C and shows a:capacity retention of 82.1% after 5000 cycles at an ultrahigh rate of 50 C, suggesting the remarkable rate capability and long cyclicity, Surprisingly, a reversible capacity of 91.1 mAh g(-1) is maintained after 1000 cycles at 5 C under the elevated temperature of SS C. The approach of nitrogen and sulfur dual doped carbon-coated Na3V2(PO4)(3) provides an effective and promising strategy to enhance the ultrahigh rate and ultralong life property of cathode, which can be used for large-scale commercial production in sodium ion batteries.

关键词

作者关键词:sodium ion batteries; cathode; Na3V2(PO4)(3); nitrogen and sulfur dual doping; rate property

作者信息

作者信息

通讯作者地址:Yang, CH (通讯作者)

显示更多South China Univ Technol, Guangzhou Key Lab Surface Chem Energy Mat, New Energy Res Inst, Sch Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China.


地址:

显示更多[ 1 ] South China Univ Technol, Guangzhou Key Lab Surface Chem Energy Mat, New Energy Res Inst, Sch Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China
显示更多[ 2 ] South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Guangdong, Peoples R China
显示更多[ 3 ] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA


电子邮件地址:esyangc@scut.edu.cn

出版商

AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA

类别分类

类别 / 分类

研究方向:Science & Technology - Other Topics; Materials Science

Web of Science 类别:Nanoscience & Nanotechnology; Materials Science, Multidisciplinary