Phase transition and hydrogen storage properties of Mg17Ba2 compound

时间:2018-05-25作者:浏览量:36


标题

Phase transition and hydrogen storage properties of Mg17Ba2 compound

作者

作者:Wu, DF (Wu, Daifeng)[1,2 ]; Ouyang, LZ (Ouyang, Liuzhang)[1,2,3 ]; Wu, C (Wu, Cong)[1,2 ]; Gu, QF (Gu, Qinfen)[3 ]; Wang, H (Wang, Hui)[1,2 ]; Liu, JW (Liu, Jiangwen)[1,2 ]; Zhu, M (Zhu, Min)[1,2 ]

期刊信息


JOURNAL OF ALLOYS AND COMPOUNDS


卷:690

页:519-522

DOI:10.1016/j.jallcom.2016.08.159

出版年:JAN 5 2017

文献类型:Article

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摘要

Mg17Ba2 hydrogen storage alloy was obtained by induction melting, and its hydrogen storage properties and phase transitions have been investigated. The reversible hydrogen capacity of Mg17Ba2 compound was 4.0 wt% H-2. A three-step dehydrogenation mechanism was revealed for the first time, and a new hydride (Ba2Mg7H18) was discovered during the dehydrogenation process. Enthalpy and entropy changes for the dehydrogenation of Mg17Ba2 were also calculated. (C) 2016 Elsevier B.V. All rights reserved.

关键词

作者关键词:Energy storage and conversion; Magnesium hydrogen storage alloys; Metals and alloys; Phase transformation

作者信息

作者信息

通讯作者地址:Ouyang, LZ (通讯作者)

显示更多South China Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China.


地址:

显示更多[ 1 ] South China Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China
显示更多[ 2 ] South China Univ Technol, China Australia Joint Lab Energy Environm Mat, Guangzhou 510641, Guangdong, Peoples R China
      [ 3 ] Australian Synchrotron, 800 Blackburn Rd, Clayton, Vic 3168, Australia


电子邮件地址:meouyang@scut.edu.cn

出版商

ELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLAND

类别分类

类别 / 分类

研究方向:Chemistry; Materials Science; Metallurgy & Metallurgical Engineering

Web of Science 类别:Chemistry, Physical; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering