Ammonia borane modified zirconium borohydride octaammoniate with enhanced dehydrogenation properties

时间:2018-05-25作者:浏览量:41


标题

Ammonia borane modified zirconium borohydride octaammoniate with enhanced dehydrogenation properties

作者

作者:Huang, JM (Huang, Jianmei)[1,4 ]; Tan, YB (Tan, Yingbin)[2 ]; Gu, QF (Gu, Qinfen)[3 ]; Ouyang, LZ (Ouyang, Liuzhang)[1,4 ]; Yu, XB (Yu, Xuebin)[2 ]; Zhu, M (Zhu, Min)[1,4 ]

期刊信息


JOURNAL OF MATERIALS CHEMISTRY A


卷:3

期:10

页:5299-5304

DOI:10.1039/c4ta05328a

出版年:2015

文献类型:Article

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摘要

A new complex system, Zr(BH4)(4)center dot 8NH(3)-nNH(3)BH(3) (n = 2, 3, 4, 5), was prepared via ball milling of Zr(BH4)(4)center dot 8NH(3) and NH3BH3 (AB). The combination strategy effectively suppressed ammonia release and reduced the dehydrogenation temperature when compared to the individual compounds. In the optimized composition, Zr(BH4)(4)center dot 8NH(3)-4AB, the hydrogen purity was improved to 96.1 mol% and 7.0 wt% of hydrogen was released at 100 degrees C. These remarkable improvements are attributed to the interaction between AB and the NH3 group in Zr(BH4)(4)center dot 8NH(3), which enables a more active interaction of H delta+center dot center dot center dot H-delta. These advanced dehydrogenation properties suggest that Zr(BH4)(4)center dot 8NH(3)-4AB is a promising candidate for potential hydrogen storage applications.

关键词

KeyWords Plus:HYDROGEN-STORAGE; DECOMPOSITION; GENERATION; BEHAVIOR; HYDRIDES; COMPLEX; SYSTEM

作者信息

作者信息

通讯作者地址:Ouyang, LZ (通讯作者)

显示更多S China Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China.


地址:

显示更多[ 1 ] S China Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China
显示更多[ 2 ] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
      [ 3 ] Australian Synchrotron, Clayton, Vic 3168, Australia
显示更多[ 4 ] S China Univ Technol, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Guangdong, Peoples R China


电子邮件地址:meouyang@scut.edu.cn

出版商

ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND

类别分类

类别 / 分类

研究方向:Chemistry; Energy & Fuels; Materials Science

Web of Science 类别:Chemistry, Physical; Energy & Fuels; Materials Science, Multidisciplinary