Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

标题

Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

作者

作者:Huang, JM (Huang, Jianmei)^[1,2 ]; Tan, YB (Tan, Yingbin)^[3 ]; Su, JH (Su, Jiahao)^[3 ]; Gu, QF (Gu, Qinfen)^[4 ]; Cerny, R (Cerny, Radovan)^[5 ]; Ouyang, LZ (Ouyang, Liuzhang)^[1,2 ]; Sun, DL (Sun, Dalin)^[3 ]; Yu, XB (Yu, Xuebin)^[3 ]; Zhu, M (Zhu, Min)^[1,2 ]

期刊信息

摘要

A new metal borohydride ammoniate (MBA), Zr(BH4)(4)center dot 8NH(3), was synthesized via ammoniation of the Zr(BH4)(4) crystal. Zr(BH4)(4)center dot 8NH(3) has a distinctive structure and the highest coordination number of NH3 groups among all the known MBAs. This compound could quickly dehydrogenate at 130 degrees C, enabling it a potential hydrogen storage material.

关键词

KeyWords Plus:HYDROGEN-STORAGE; METAL BOROHYDRIDES; POWDER DIFFRACTION; RECENT PROGRESS; HYDRIDES; DECOMPOSITION; STABILITY; BEHAVIOR; COMPLEX

作者信息

作者信息

通讯作者地址:Ouyang, LZ (通讯作者)

S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China.   增强组织信息的名称     South China University of Technology

地址:

	[ 1 ] S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China   增强组织信息的名称     South China University of Technology
	[ 2 ] S China Univ Technol, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China   增强组织信息的名称     South China University of Technology
	[ 3 ] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China   增强组织信息的名称     Fudan University
	[ 4 ] Australian Synchrotron, Clayton, Vic 3168, Australia
	[ 5 ] Univ Geneva, DQMP, Lab Cristallog, CH-1211 Geneva, Switzerland   增强组织信息的名称     University of Geneva

电子邮件地址:meouyang@scut.edu.cn; yuxuebin@fudan.edu.cn

出版商

ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND

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