Facile synthesis of ultrathin-shell graphene hollow spheres for high-performance lithium-ion batteries

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标题

Facile synthesis of ultrathin-shell graphene hollow spheres for high-performance lithium-ion batteries

作者

作者:Cai, DD (Cai, Dandan)[1 ]; Ding, LX (Ding, Liangxin)[1 ]; Wang, SQ (Wang, Suqing)[1 ]; Li, Z (Li, Zhong)[1 ]; Zhu, M (Zhu, Min)[2 ]; Wang, HH (Wang, Haihui)[1 ]

期刊信息


ELECTROCHIMICA ACTA


卷:139

页:96-103

DOI:10.1016/j.electacta.2014.07.014

出版年:SEP 1 2014

文献类型:Article

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摘要

In this work, ultrathin-shell graphene hollow spheres have been designed and synthesized from the graphene oxide nanosheets by a simple template assisted method without surfactant. It is found that the obtained graphene hollow spheres have a high surface area (248.3 m(2) g(-1)), ultrathin porous shells (5 nm) and an interconnected structure. More strikingly, the as-prepared graphene hollow spheres exhibit outstanding electrochemical performance as an anode material for lithium-ion batteries. Even at a high current density of 5000 mAg(-1), a high reversible specific capacity of 249.3 mAh g(-1) can be achieved. Furthermore, after 100 cycles, about 97.1% of the specific capacity is maintained at a high current density of 1000 mAg(-1). The excellent electrochemical properties could be attributed to the attractive structure advantages of the graphene hollow spheres including the high surface area, ultrathin porous shells and an interconnected structure. (C) 2014 Elsevier Ltd. All rights reserved.

关键词

作者关键词:Graphene; Hollow spheres; Anode materials; Lithium-ion batteries

作者信息

作者信息

通讯作者地址:Wang, HH (通讯作者)

显示更多S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China.


地址:

显示更多[ 1 ] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
显示更多[ 2 ] S China Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China


电子邮件地址:lxding@scut.edu.cn; hhwang@scut.edu.cn

出版商

PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

类别分类

类别 / 分类

研究方向:Electrochemistry

Web of Science 类别:Electrochemistry