Facile synthesis of Ge@FLG composites by plasma assisted ball milling for lithium ion battery anodes

时间:2018-05-25作者:浏览量:169


标题

Facile synthesis of Ge@FLG composites by plasma assisted ball milling for lithium ion battery anodes

作者

作者:Ouyang, LZ (Ouyang, Liuzhang)[1,2 ]; Guo, LN (Guo, Lina)[1,2 ]; Cai, WH (Cai, Weihua)[3 ]; Ye, JS (Ye, Jianshan)[3 ]; Hu, RZ (Hu, Renzong)[1,2 ]; Liu, JW (Liu, Jiangwen)[1,2 ]; Yang, LC (Yang, Lichun)[1,2 ]; Zhu, M (Zhu, Min)[1,2 ]

期刊信息


JOURNAL OF MATERIALS CHEMISTRY A


卷:2

期:29

页:11280-11285

DOI:10.1039/c4ta01267d

出版年:2014

文献类型:Article

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摘要

Efficient production of graphene or its germanium (Ge) composites remains a challenge, although Ge nanoparticles (NPs) wrapped with graphene are suitable for preventing the large volume change of anodes for lithium ion batteries during Li uptake and release processes. This work is the first simple, efficient in situ synthesis of Ge NPs, with an excellent structure, wrapped with few-layer graphene sheets (abbreviated as Ge@FLG) from commercial Ge powders and natural graphite by a one-step ball-milling process assisted by dielectric-barrier discharge plasma. Because of their unique structure, Ge@FLG electrodes exhibit better electrical conductivity, low initial capacity loss, good cycling capability, and rate resilience compared with Ge@C electrodes prepared by conventional milling. This work highlights a new method for the efficient production of Ge@FLG composites and their applications in lithium ion batteries and in other technologies.

关键词

KeyWords Plus:DISCHARGE PLASMA; GRAPHENE; PERFORMANCE; STORAGE; FILMS; NANOCOMPOSITE; CHALLENGES; ELECTRODES; CAPACITY; AREA

作者信息

作者信息

通讯作者地址:Zhu, M (通讯作者)

显示更多S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China.


地址:

显示更多[ 1 ] S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China
显示更多[ 2 ] S China Univ Technol, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China
显示更多[ 3 ] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China


电子邮件地址:memzhu@scut.edu.cn

出版商

ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND

类别分类

类别 / 分类

研究方向:Chemistry; Energy & Fuels; Materials Science

Web of Science 类别:Chemistry, Physical; Energy & Fuels; Materials Science, Multidisciplinary