关于举行德国维尔茨堡大学Frank Würthner教授学术报告的通知
报告题目：Dyes and Pigments for Organic Electronics & Photovoltaics
报 告 人：Frank Würthner 教授 （Universität Würzburg）
报告时间：2017年4月13日（周四）下午3:00
报告地点：北区发光材料与器件国重 N308A报告厅
报告摘要：
In recent years we could witness a shift of paradigm in organic semiconductor research towards dyes and color pigments. Thus, after two decades of research focused on conjugated polymers and oligothiophene as well as acene based organic semiconductor molecules most recent work in several laboratories demonstrated high charge carrier mobilities > 1 cm2V-1s-1 for various classes of dyes and pigments. These results are remarkable owing to the presence of dipolar functional groups in these compounds which was believed to result in large reorganization energies and bad transport properties. Obviously this view needs to be reassessed. In particular for organic photovoltaics the success of several low band gap conjugated oligomers and polymers (containing dipolar functional groups) as well as small molecule based organic colorants appears highly promising.
In this lecture I will give an overview on our work on n-type organic semiconductors based on naphthalene and perylene bisimides and p-type organic semiconductors based on merocyanines, squaraines and diketopyrrolopyrroles. A particular focus will be given on the most unusual highly dipolar merocyanine dyes which exhibit outstanding performance in bulk heterojunction solar cells with PCE > 6%. Our recent demonstration of hole mobilities up to 1.3 cm2V-1s-1 in organic thin film devices and up to 8.6 cm2V-1s-1 in organic single crystals clearly corroborates the view that the presence of dipolar groups does not imply bad transport properties. Dyes and colorants are accordingly very versatile for organic electronics and organic photovoltaics.
References
[1] M. Gsänger, D. Bialas, L. Huang, M. Stolte, F. Würthner, Adv. Mater. 2016, 28, 3615–3645: Organic Semiconductors based on Dyes and Color Pigments.
[2] S. Seifert, K. Shoyama, D. Schmidt, F. Würthner, Angew. Chem. Int. Ed. 2016, 55, 6390–6395: An Electron-Poor C64 Nanographene by Palladium-Catalyzed Cascade C–C Bond Formation: One-Pot Synthesis and Single-Crystal Structure Analysis
[3] A. Arjona-Esteban, J. Krumrain, A. Liess, M. Stolte, L. Huang, D. Schmidt, V. Stepanenko, M. Gsänger, D. Hertel, K. Meerholz, F. Würthner, J. Am. Chem. Soc. 2015, 137, 13524–13534: Influence of Solid-State Packing of Dipolar Merocyanine Dyes on Transistor and Solar Cell Performances
[4] T. He, M. Stolte, C. Burschka, N. H. Hansen, T. Musiol, D. Kälblein, J. Pflaum, X. Tao, J. Brill, F. Würthner, Nat. Commun. 2015, 6, 5954: Single-Crystal Field-Effect Transistors of New CI2-NDI Polymorph Processed by Sublimation in Air
个人简历：
| Name | Prof. Dr. Frank Würthner | |||
| Contact | Universität Würzburg | |||
| Institut für Organische Chemie & | ||||
| Center for Nanosystems Chemistry (CNC) | ||||
| D-97074 Würzburg, Germany | ||||
| Phone/Fax: +49 931 31-85340 / 31-84756 | ||||
| Date of birth | June 27, 1964 | |||
| Education | 2001 | Habilitation in Organic Chemistry, U Ulm | ||
| 1990-1994 | Dr. rer.nat., U Stuttgart: Synthesis and Properties of Donor-Acceptor-substituted Oligothiophenes | |||
| 1984-1990 | Study of Chemistry, U Stuttgart
| |||
| Academic Career | since 2002 since 2010 | Professor, Chair of Organic Chemistry II, U Würzburg Director, Center for Nanosystems Chemistry, U Würzburg | ||
| 2008/2009 | Chairs offered from KIT and U Heidelberg, Max Planck Director Position offered from MPI of Solid State Science, Stuttgart | |||
| 1997-2002 | Liebig and DFG fellow (Habilitation), U Ulm | |||
| 1995-1996 | Chemist at BASF Central Research, Ludwigshafen | |||
| 1994-1995 | Postdoc, MIT, Cambridge/MA (USA) | |||
| Research Topics | Dyes and organic semiconductors; Supramolecular chemistry, Photochemistry; Self-assembly & supramolecular polymerization; Materials for organic electronics, photonics, photovoltaics; artificial photosynthesis | |||
| Project Coordination & Editorial Work | since 2016 since 2012 | Member Board of Directors, Bavarian Polymer Institute Member Board of Directors Bavarian Research Network Solar Technologies Go Hybrid; in 2013 Coordinator | ||
| 2007-2009 | Dean Faculty of Chemistry and Pharmacy, U Würzburg | |||
| since 2015 | Associate Editor of Organic Chemistry Frontiers (Royal Society of Chemistry & Chinese Chemical Society) | |||
| since 2010 | Curator and Member of the Scientific Council of the Fonds der Chemischen Industrie | |||
| 2011-2014 | Member European Research Council Panel 5 (Consolidators) | |||
| since 2010 | Editorial Advisory Board Member Asian J. of Organic Chemistry(Wiley-VCH), J. of Organic Chemistry (ACS), J. of Inclusion Phenomena and Macrocyclic Chemistry (Springer) | |||
| Honors and Awards | ||||
| 2016 2016 | Member German National Academy of Science Leopoldina Elhuyar-Goldschmidt Award (Royal Chemical Society Spain) | |||
| 2016 | Elsevier Lecture Award (Japanese Photochem. Association) | |||
| 2016 | Fellow of the Royal Society of Chemistry (FRSC) | |||
| 2015 | Emanuel Vogel Lecture Award (University of Cologne) | |||
| since 2014 | Listed as Thomson Reuters Highly Cited Researcher | |||
| 2014
| K. S. Krishnan Lecture Award (Indian Association of the Cultivation of Science, Kolkata) | |||
| 2010/11 | Visiting Professor at the Institute of Chemistry, Chinese Academy of Science (Beijing) | |||
| 2002 | Arnold Sommerfeld Award (Bavarian Academy of Science) | |||
Publications > 350 publications, h-index: 83
