
Following their groundbreaking study in inorganic perovskite tandem photovoltaics published in Nature in 2024, Professor Yan Keyou's research team at SCUT has achieved a major advancement inhigh-energy-density lithium metal batteries. Their research outcome has been published in the world'sleading science journal Nature under the title 'Li₂ZrF₆-Based Electrolytes for Durable Lithium MetalBatteries'.
Lithium metal batteries are widely regarded as one of the most promising candidates for nextgeneration energy storage systems. However, the conventional carbonate-based electrolytes used inlithium-ion batteries remain fundamentally incompatible with lithium metal batteries. Consequently,constructing an ideal solid electrolyte interphase at the lithium metal anode interface has consistentlyrepresented a critical challenge in this field of research.
To address this challenge, SCUT researchers have demonstrated the feasibility of using t-Li₂ZrF₆ crystalsto construct an optimal solid electrolyte interphase. They proposed using an electric field to drive thephase transition from m-Li₂ZrF₆ to t-Li₂ZrF₆ for solid electrolyte interphase formation. Experimentalresults show that this approach not only leverages t-Li₂ZrF₆'s superior electron-insulating properties toprevent electron-induced breakdown of the solid electrolyte interface, thereby suppressing electrolytedecomposition, but also facilitates rapid Li⁺ ion transport and thereby significantly enhances the ratecapability of lithium metal batteries.
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