Topic: Dielectric Phenomena in Polymers and Multilayered Dielectric Films
Speaker: Prof Lei Zhu, Case Western Reserve University
Time: 9:00, May 31, 2017
Venue: Room 331, Building 25, Wushan Campus
Biography:
Professor Lei Zhu received his B.S. degree in Materials Chemistry in 1993 and M.S. degree in Polymer Chemistry and Physics in 1996 from Fudan University. He received his Ph.D. degree in Polymer Science from University of Akron in 2000. After two-year post-doctoral experience at the Maurice Morton Institute, University of Akron, he joint Institute of Materials Science and Department of Chemical, Materials and Biomolecular Engineering at University of Connecticut, as an assistant professor. In 2007, he was promoted to associate professor with tenure. In 2009, he moved to Department of Macromolecular Science and Engineering at Case Western Reserve University as an Associate Professor. In 2013, he was promoted to full Professor. His research interests include high κ polymer and organic-inorganic hybrid nanomaterials for high energy density capacitor applications, development of artificial antibody as nanomedicines, and supramolecular self-assembly of discotic liquid crystals. He is recipient of NSF Career Award, 3M Non-tenured Faculty Award, DuPont Young Professor Award, and Rogers Teaching Excellence Award. He is author and co-author of 148 refereed journal publications and 5 book chapters. He delivered over 130 invited talks and 45 contributed presentations, and his total citation is ~6000 times with an h-index of 46 (Google Scholar)
Abstract:
High dielectric constant and low dielectric loss are desirable electrical properties for next generation polymer dielectrics that show promise for applications in pulsed power, power electronics, and printable electronics. Unfortunately, the dielectric constant of polymers is often limited to 2-5, much lower than that of inorganic dielectrics, because of the nature of hydrocarbon covalent bonds for electronic and atomic polarizations. It is essential to understand the fundamental physics of different types of polarization and the associated loss mechanisms in polymers. In this perspective article, we discuss the characteristics of each polarization and explain how to enhance the polarization using rational molecular designs without causing significant dielectric losses. Among various approaches for high dielectric constant and low loss polymers, the multilayer film technology is of particular interest because a multilayer film is a unique one-dimensional system with tailored material choices, layer thicknesses, and interfaces. By minimizing the disadvantageous polarizations and enhancing the advantageous polarizations, multilayer films hold promise as advanced dielectrics for future polymer film capacitors.