Closed loops for hydrogen storage: Hydrolysis and regeneration of metal borohydrides

Closed loops for hydrogen storage: Hydrolysis and regeneration of metal borohydrides

作者:Zhu, YY (Zhu, Yongyang) [1] ; Li, JD (Li, Jianding) [2] ; Yang, LM (Yang, Limei) [3] ; Yang, XS (Yang, Xu-Sheng) [5] ; Zhou, Q (Zhou, Qing) [1] ; Tang, RH (Tang, Renheng) [1] ; Shen, SY (Shen, Shaoyang) [4] ; Ouyang, LZ (Ouyang, Liuzhang) [4]

 (由 Clarivate 提供) 

卷563

文献号232833

DOI10.1016/j.jpowsour.2023.232833

出版时间APR 15 2023

在线发表FEB 2023

已索引2023-03-27

文献类型Review

摘要

Metal borohydrides (M(BH4)n) are extensively studied due to their high hydrogen storage capacities via hydrolysis. However, it is challenging to develop a closed loop of hydrolysis and regeneration of M(BH4)n that is of low-cost and high-efficiency. In this work, we overview the state-of-the-art advances in both hydrolysis and regeneration processes of Li(Na)BH4 and Mg(BH4)2. In particular, a special focus is placed on NaBH4 hydrolysis with respect to catalysts, capacity, kinetics and thermodynamics. NaBH4 regeneration is also discussed in terms of synthesis techniques, the sources of boron and hydrogen, and the reducing agents. There are great advances in the development of catalysts in facilitating hydrogen evolution. Critically, low-cost transition metal-based catalysts is effective in catalyzing the hydrolysis. Catalyzed hydrogen evolution can meet the requirement of PEMFC in small devices. For future applications in large scale, more research is needed to optimize the performance to deliver the required rates and quantities. Cost becomes more paramount for large-scale applications and effective

关键词

作者关键词HydrolysisRegenerationMetal borohydrideHydrogen storageHydrogen production

Keywords PlusSOLID SODIUM-BOROHYDRIDEMAGNESIUM BOROHYDRIDECATALYZED-HYDROLYSISCOMPLEX HYDRIDESCOBALT NANOPARTICLESAMORPHOUS MG(BH4)(2)STATE NABH4GENERATIONCARBONRU

作者信息

通讯作者地址

Li, Jianding

(通讯作者)

Huzhou Univ, Sch Sci, Huzhou Key Lab Mat Energy Convers & Storage, Huzhou 313000, Peoples R China

通讯作者地址

Yang, Limei

(通讯作者)

Univ Technol Sydney, Sch Civil & Environm Engn, Sydney, NSW 2007, Australia

通讯作者地址

Ouyang, Liuzhang

(通讯作者)

South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China

所属机构

South China University of Technology

地址

1 Guangdong Acad Sci, Inst Resources Utilizat & Rare Earth Dev, State Key Lab Rare Met Separat & Comprehens Utiliz, Guangdong Prov Key Lab Rare Earth Dev & Applicat, Guangzhou 510650, Peoples R China

2 Huzhou Univ, Sch Sci, Huzhou Key Lab Mat Energy Convers & Storage, Huzhou 313000, Peoples R China

3 Univ Technol Sydney, Sch Civil & Environm Engn, Sydney, NSW 2007, Australia

4 South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Peoples R China

5 Hong Kong Polytech Univ, Res Inst Adv Mfg, Dept Ind & Syst Engn, Hung Hom,Kowloon, Hong Kong, Peoples R China

电子邮件地址jiandingli@zjhu.edu.cnlimei.yang@uts.edu.aumeouyang@scut.edu.cn

类别/分类

研究方向ChemistryElectrochemistryEnergy & FuelsMaterials Science

引文主题

2 Chemistry

2.282 Hydrogen Chemistry & Storage

2.282.594 Hydrogen Storage

Sustainable Development Goals

07 Affordable and Clean Energy

Web of Science 类别Chemistry, PhysicalElectrochemistryEnergy & FuelsMaterials Science, Multidisciplinary