报告主题:POLYMERISATION-INDUCED SELF-ASSEMBLY
报告人:Prof. Steven P. Armes,Fellow of the Royal Society,University of Sheffield
邀请人:软物质研究院
报告时间:2019年11月28日(星期四)上午10:00
报告地点:北区科技园2号楼软物质研究院324报告厅
欢迎广大师生踊跃参加!
分子科学与工程学院
华南软物质科学与技术高等研究院
2019年11月18日
报告摘要:
Polymerisation-induced self-assembly (PISA) is a highly versatile, potentially scalable platform technology that enables the efficient and rational synthesis of block copolymer nanoparticles of various morphologies directly in the form of concentrated dispersions. The basic principles of PISA are generic: a wide range of diblock copolymer nano-objects can be readily prepared in either water, ethanol or n-alkanes. In PISA, a soluble precursor 'A' block is chain-extended using a second monomer that forms an insoluble 'B' block in the chosen solvent. As this second 'B' block grows in the monomer/solvent reaction mixture, micellar nucleation occurs at some critical chain length, leading to the formation of sterically-stabilized nanoparticles. Depending on the relative volume fractions of the 'A' and 'B' blocks, the copolymer morphology can be either spheres, worms or vesicles.
This talk will focus mainly on the RAFT aqueous dispersion polymerisation of 2-hydroxypropyl methacrylate (HPMA), which serves as a convenient model system for understanding PISA formulations.
报告人简介:
Academic Research Record and Professional Activities. > 610 publications in refereed journals (H-index = 109; > 34,000 citations). Named inventor on 25 patents. Invited to join ten journal editorial boards, including Langmuir, Macromolecules, Biomacromolecules, Polymer Chemistry, J. Materials Chemistry, Macromol. Rapid Commun. and J. Colloid Interface Sci.
Grants, Awards and Prizes. ERC Advanced Investigator grant-holder (2013-2018). Received 45 EPSRC research grants, including 3 consecutive Platform Grants and a current £1.67 M Particle Technology Fellowship. Awarded the 2018 Royal Society Armourers & Brasiers’ Company Prize, the 2018 Macro Group UK medal, the 2017 ECIS Solvay prize, the 2016 DSM Materials Science award, the 2014 RSC Interdisciplinary Prize, the 2013 RSC Tilden Prize, the RSC 2010 Peter Day Soft Matter award and the 2007 RSC Macro Group Medal. Delivered the RSC 2014 Thomas Graham Lecture and the 2015 Colloid & Polymer Science Lecture for the German Colloid Society. Recipient of a Royal Society/Wolfson Research Merit Award (2005-2009).