Elastomer Reinforced with Innate Sulfur-Based Cross-Links as Ligands

Xuhui Zhang, Shuangjian Yu, Zhenghai Tang, Baochun Guo*

ABSTRACT: Although the incorporation of sacrificial bonds into an elastomer is an effective way to provide a combination of high strength and high fracture toughness, this method normally involves complicated chemical processes. The coordination between metal ions and polysulfides has been documented. However, the potential of polysulfide structures in vulcanizates as ligands has long been neglected. Using innate sulfur-based cross-links, we show how weak and nonpolar elastomers achieve significant reinforcement without modification of the backbone. By simply soaking vulcanizates into solutions containing metal ions, dual ions are simultaneously introduced into the vulcanizate to generate coordinations with different bond strengths, resulting in an unprecedented high modulus. Overall, this work presents a universal yet high-efficiency reinforcing strategy to prepare high-performance elastomers without additional chemical modifications, which should promote comprehensive research and industrial application of sacrificial bond strategies for elastomers.

文章链接：https://pubs.acs.org/doi/pdf/10.1021/acsmacrolett.9b00512