分子内酯键方向性对向列相液晶粘弹系数的极限调控
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分子内酯键方向性对向列相液晶粘弹系数的极限调控
发布时间:2021-08-17        浏览次数:10

Extreme modulation of liquid crystal viscoelasticity via altering the ester bond direction

Wentao Tang, Minghui Deng, Junichi Kougo, Li Ding, Xiuhu Zhao, Yuki Arakawa*, Kenta Komatsu, Hideto Tsuji, Satoshi Aya*  

J. Mater. Chem. C. 9, 9990-9996(2021)

https://doi.org/10.1039/D1TC01636A

 

Abstract

 

The understanding of correlations between molecular details and macroscopic material behavior is a fundamental question of molecular chemistry/physics and offers practical interest in materials design with fine-property-tunability. Herein, we demonstrate extreme modulation of liquid crystal (LC) viscoelasticity triggered by a reversion of the ester bond direction in two series of sulfur-containing cyanobiphenyl-based LC dimers. They possess two oppositely directed ester linkages (i.e., C=OO or OC=O), namely COOn and OCOn, respectively, and different carbon atom numbers of the short alkylene spacers (n = 4 and 6). Unexpectedly, it has been proven that the COOn homologs exhibit extraordinarily enhanced viscoelastic properties in the fluidic nematic (N) phase (up to about 1000 times) compared with their OCOn counterparts. Besides, dielectric spectroscopy revealed that the degree of the collective orientational fluctuation is significantly affected by reversing the ester bond direction, suggesting the existence of heliconical clusters embedded in the N state. Finally, we have proposed a novel eco-driving LC memory device based on a pulse-electric-field driving method using COO4 with an extremely high rotational viscosity.

 

论文链接:

https://pubs.rsc.org/en/content/articlelanding/2021/TC/D1TC01636A

 

 

 

 

 


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